L.M.I.M. (UPDATING)
About Us
The Molecular Materials and Interfaces Laboratory (MMIL) develops several investigation themes since 2004. In the present section you will texts and tutorial videos about these subjects. (English subs to come a soon as possible). Please activate the menus on the top green bar.
Find us on Instagram at @usp_lmim and on Google Earth: 21°10’4.24″S 47°50’54.68″O
Research interests
Macrocycles|Membranes|Molecular materials|Light conversion|Nanostructures|Tutorial Videos|Papers|Patents|People
Macrocycles and Inclusion compounds
Cucurbiturils, bambusurils, pyrogallolarenes, resorcinarenes, hemi-cucurbiturils, as well as their derivatives. Our focus are inclusion compounds with halogens for organic synthesis, the metallic complexes of these macrocycles for catalysis, the inclusion compounds with dyes for photodynamic therapy, illicit drugs and food components for electrochemical and optical sensors, as well as the interactions between these cavities and simple ions for the preparation of semipermeable membranes. (Refs. 1-3,8,9,15)
Special catalysts
Polymeric Membranes
Nanofiltration membranes and pervaporation membranes are extremely useful for water purification/treatment, fuel cell, gas separation and CO2 trapping among a myriad of applications. These membranes are named CUBION. We prepare too CUBION-based polymeric composites with artificial molecular channels, that are able to discriminate permeation of individual chemical species by size, by charge and/or solvophilicity.
Nanofiltration membranes in action.
We prepare special absorbers to treat effluents, and to get rid of oil (see film bellow), heavy metals and emerging contaminants as well.
CUBION sponges are very efficient too, and they can be shaped in several forms and sizes. As they float, they act the same way as CUBION films towards oil absorption. The oil is recovered and the CUBION componentes may be reused and recycled by simple processes.
CUBION sponge before and after absorbing crude oil |
Modified electrodes with CUBION
Molecular Materials and molecular devices
In the field of molecular materials we focus naphthalene imides and diimides, as well as hypericin and azulene to prepare functional materials as thin films, MOFs, metallic complexes and all kinds of solid phases for applications in electronics, energy conversion and energy storage.
Fluorophores and Light conversion systems
Nanostructures
Peer-reviewed papers
Click on the numbers for the papers…
56. Dias, G.B.D.; Lago, V.G.; Demets, G.J.F."A note on false Scott-test positives for uril-based macrocycles" J. Inclusion Phenom. Macroc. Chem. 103 (2023) 451-453. 55. Floriano, G.L.; Demets, G.J.F.; Souza, L.R.R."Chromium removal from water and tannery effluent with Cucurbit[6]uril" Int. J. Environ. Sci. Technol. (2023) 10.1007/s13762-023-05172-5
54. Cicolani, R.S.; de Oliveira, A.G.S.; Batista, A.P.D.; Demets, G.J.F. "Trihalide-included (I2, Br2 and IBrCl-) bambus[6]urils in halogenation and iodine-catalysed reactions" J. Inclusion Phenom. Macroc. Chem. 103 (2023) 81-87.
53. Mateus, D.B.G.; Batista, A.P.D.; Souza, S.D.; Demets, G.J.F.; Nikolaou, S. "Solvatochromism and solution π-stacking of N-(4-pyridyl)-1,8-naphthalimide and its corresponding triruthenium coordination complex" Spectrochim Acta A 292 (2023) 122420.
52. Silva, F. D. A.; Lima, G.; Demets, G. J. F. "Naphthalene Diimides and Vanadium Pentoxide Composite Electrodes for Lithium Ion Batteries" Russ. J. Electrochem. 58-6 (2022) 433.
51. Demets, G. J. F. "What is Expected from a Reviewer?" Orbital Electr. J. Chem. 13(5) (2021) 425.
50. Soares, R. S. B.; Souza, L. R. R.; Bertolucci, M. M.; Oliveira, A.; Demets, G. J. F.; Araki K. "Critical Parameters for Green Glycoluril Synthesis" Russ. J. Gen. Chem. 91-4 (2021) 739-742.
49.Cicolani, R. S.; Souza, L. R. R.; Dias, G. B. S.; Gonçalves, J. M. R.; Abrahão, I. S.; Silva, V. M.; Demets, G. J. F. "Cucurbiturils for environmental and analytical chemistry"J. Inclusion Phenom. Macroc. Chem. 99 (2021) 1-12.
48.Demets, G. J. F.; Araki, K. "Living, Social, Small and Challenging" J. Braz. Chem. Soc., 31-11 (2020) 2175. Editorial
47.Carvalho, J. C. C. ; Cicolani, R. S. ; Demets, G. J.F. . "Improvements in Methyl- Bambus[6]uril Synthesis Yield." J. Braz. Chem. Soc., (2020) 31-11. 46. Cicolani, R. S. ; de Oliveira Fo., A. G. S.; de Lima Batista, A. P. ; et Demets, G. J. F. "Formation of the non-classical interhalide ion [I2Cl]− in methyl-bambus[6]uril cavity” N. J. Chem. 44 (2020) 2697-2700.
45. Braz Gonçalves, D. M. ; da Silva Souza, S. ; de Bacchi Silva, R. J. ; de Lima Batista, A. P. ; Cicolani, R. S. ; Murie, V. E. ;
Nishimura, R. H. ; Clososki, G. C. ; de Oliveira Fo.,A. G. S.; Demets, et G. J. F. ; Nikolaou S. "Assessment of the electronic
structure of a triruthenium acetate-pyridylnaphthalimide cluster"J. Photochem. Photobiol. A Chem. 391 (2020) 112361
44. Chowdhury, S. ; Nassar, Y. ; Guy, L. ; Frath, D. ; Chevallier, F. ; Dumont, E. ; Ramos, A. P. ; Demets, G. J. F. ;
Bucher, C. "Photo/redox-responsive 2D-Supramolecular assembly involvingCucurbit[8]uril and a star-shaped porphyrin tecton”
Electrochim. Acta 316 (2019) 79-92.
43. Cicolani, R. S. ; et Demets, G. J. F. "A Família das Bambus[n]urilas.” Quimica Nova 41 (2018) 912-919.
42. De Araújo Silva, F. ; Cicolani, R. S. ; Lima, G. ; Huguenin, F. ; Demets, G.J.F. "Enhanced Li charge storage in naphthalene
diimide/vanadium pentoxide intercalates.” RSC Adv. 8(2018) 24029-24035.
41. Moraes, T. B. F. ; Schimidt, M. F. R. A. ; Bacani, R. ; Weber, G. ; Politi, M. J. ; Castanheira, B. ; Brochsztain, S. ;
De Araújo Silva, F. ; Demets, G. J. F. ; et Triboni, E. R. "Polysilsesquioxane naphthalenediimide thermo and photochromic gels.”
J. Luminesc. 204 (2018) 685691.
40. Correia, H. D. ; Chowdhury, S. ; Ramos, A. P. ; Guy, L. ; Demets, G. J. F. ; et Bucher, C. "Dynamic Supramolecular Polymers
Built From Cucurbit[n]urils And Viologens.” Polym. Intern. 2018 (2018) 117.
39. Cicolani, R. S. ; Job, A. E. ; Tonin, F. G. ; Correia, H. D. ; et Demets, G. J. F. "Thermal behaviour of bambus[6]uril
and its chloride caviplex.” J. .Therm. Anal. Calorim. (Online), 2018 (2018) 15.
38. Santos, G. de C.; Barros, A. L.; De Oliveira, C. A. F.; Da Luz, L. L.; Da Silva, F. F. ; Demets, G. J. F. ; et Alves Jr., S.
"New Composites LnBDC@AC and CB[6]@AC: From Design toward Selective Adsorption of Methylene Blue or Methyl Orange.”
Plos One 12 (2017) e0170026.
37. Castaldelli, E. ; Jayawardena, I. K. D. G. ; Cox, D. C. ; Clarkson, G. J. ; Walton, R. I. ; Lequang, L. ; Chauvin, J. ;
Silva, S. R. P. ; et Demets, G. J. F. "Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metalorganic
framework.” Nature Commun. 8 (2017) 1.
36. de Menezes, M. M. T. ; Balbino, M. A. ; Castro, A. S. ; Eleotério, I. C. ; Demets G. J. F. ; de Oliveira, O. V. ; Ipólito, A. J. ;
McCord, B. R. ; et de Oliveira, M. F. "Chemically Modified Piezoelectric Devices to Detect Seized Marijuana and Cocaine Samples:
A New Tool for Forensic Chemistry” SM J. Forens. Res. Criminol. 1-1(2017) 1003-1010.
35. Correia, H. D. ; Cicolani, R. S. ; Moral, R. F. ; et Demets, G. J.F. "Easy Synthesis of trans-4,5- Dihydroxy-2-imidazolidinone
and 2,4-Dimethylglycoluril.” Synthesis (Stuttgart) 48 (2015) 210-212.
34. Reddy, R. K. K. ; Cavallini, T. S. ; Demets, G. J. F. ; et Silva Jr., L.F. "Bromide and Iodide-cucurbit[6]uril Complexes:
Preparation and Applications in Synthetic Organic Chemistry.” N. J. Chem. 38 (2014) 2262-2264.
33. Bolfarini, G. C. ; Siquieira-Moura, M. P. ; Demets, G.J.F. ; Tedesco, A. C. "Preparation, characterization, and in vitro
phototoxic effect of zinc phthalocyanine cucurbit[7]uril complex encapsulated into liposomes.” Dyes Pigm., 100 (2014) 162-167.
32. de Araújo Silva, F. ; Huguenin, F. ; de Lima, S. M. ; et Demets, G. J. F. "Lithium Ion Electrochemical Insertion in
Vanadium Pentoxide/Cucurbit[6]uril Intercalates.”, Inorg. Chem. Front. 1 (2014) 495-502.
31. Sousa e Silva, F. C. ; de Lima, S. M. ; et Demets, G. J. F. "Reusable cucurbit[6]uril-loaded poly(urethane) sponges
for oily waters treatment” RSC Adv. 4 (2014) 58796-58799.
30. Tadini, M. C. ; Agostinho, T. C. ; Dias L.G. ; Demets, G.J.F. ; et Oliveira, M. F. "Developing electrodes chemically
modified with cucurbit[6]uril to detect 3,4 methylenedioxymethamphetamine (MDMA) by voltammetry.
Electrochim. Acta, 121 (2014) 188-193.
29. Silva, L. F. S. ; Leroux, F. ; Taviot-Guého C. ; Valim, J. B. ; et Demets, G.J.F. "Single Step Preparation of Regular Zincite
Nanospheres Using Cucurbit[7]uril. “ Synth. React. Inorg. Metal-Organ. Nano-Metal Chem., 43 (2013) 1078-1082.
28. Rozanski, L. J. ; Castaldelli, E. ; Sam, F. L. M. ; Mills, C. A. ; Demets, G. J. F.; et Silva, S. R. P.
"Solution processed naphthalene diimide derivative as electron transport layers for enhanced brightness and efficient polymer light
emitting diodes.” J. Mater. Chem. C, 1 (2013) 3347-3352.
27. Tovani, C. B. ; Souza, J. F. V. ; Cavallini, T. S. ; Demets, G.J.F. ; Berardi, M. B. ; Panzini, W. M. ; Ito, A. ; et Zaniquelli,
M. E. D. "Comparison between Cucurbiturils and β-cyclodextrin interactions with cholesterol molecules present in Langmuir monolayers
used as a biomembrane model.” Coll. Surf. B, Biointerf., 111 (2013) 398-406.
26. Bolfarini, G. C. ; Siqueira-Moura, M. P. ; Demets, G. J.F. ; Morais, P. C. ; et Tedesco, A. C. "In vitro evaluation of
combined hyperthermia and photodynamic effects using magnetoliposomes loaded with cucurbituril zinc phthalocyanine complex on melanoma.”
J. Photochem. Photobiol. B, Biol., 115 (2012) 1-4.
25. Teodósio, T. M. B. ; Jardim, L. V. ; Cavallini, T. S. ; et Demets, G. J.F. "Montagem de uma Célula Universal para Ensaios de Permeação
em Membranas Semipermeáveis Sólidas em Escala Laboratorial.” Orbital Electron. J. Chem., 3 (2011) 204-211.
24. Dovidauskas, S. ; et Demets, G. J.F. "300 anos de Lomonosov.” Orbital Electron. J. Chem., 3 (2011) 150-173.
23. Santos, E.M.S., Santos, L.P., et Demets, G.J.F. "Quantum Confinement in PbI2 Nanodisks Prepared with Cucurbit[7]uril.” J. Braz. Chem. Soc., 22 (2011) 1595-1600.
22. Castaldelli, E., Triboni, E.R., et Demets, G.J.F. ”Self-assembled naphthalenediimide derivative films for light-assisted
electrochemical reduction of oxygen.“ Chem. Commun. 47 (2011) 5581-5583.
21. da Silva, L.F.S., Demets, G.J.F., Taviot-Guého, C., Leroux, F., et Valim, J.B.”Unusual Incorporation of Neutral and Low Water-Soluble
Guest Molecules into Layered Double Hydroxides: The Case of Cucurbit[6 and 7]uril Inclusion Hosts.“ Chem. Mater. 23 (2011) 1350-1352.
20. de Lima, S.M., Gómez, J.A., Barros, V.P., De S. Vertuan, G., Assis, M.D.D., de Oli- veira Graeff, C.F., et Demets, G.J.F.
“A new Oxovanadium(IV)-Cucurbit[6]uril complex: Properties and Potential For Confined Heterogeneous Catalytic Oxidation Reactions.”
Polyhedron, 2 (2010) 3008-3013.
19. Triboni, E.R., Silva, M.F.P., Rodrigues, M.A., Demets, G.J.F., Dyszy, F.H., Isolani, P.C., Berci fo., P., et Politi, M.J.
“Synthesis and properties of new paramagnetic hybrid bayerite from Al(0)/naphthalene dianhydride reaction.” Mat. Res.,13, (2010)1-7.
18. Correia, H.D., et Demets, G.J.F. “Cucurbit[6]uril/PVC-based Semipermeable Membranes as Electrode Modifiers for Electrochemical
Investgation of Insoluble Substrates.” Electrochem. Commun., 11, (2009) 1928-1931.
17. Demets G.J.-F., Schneider B.V.S., Correia H.D., Gonçalves R.R., Nobre, T.M. et Zaniquelli M.E.D.” A technique to produce thin
cucurbit[6]uril films” J. Nanosci. Nanotechnol. 8 (2008) 1-4.
16. Demets G.J.-F., “Cucurbiturilas” Quimica Nova 30(5) (2007) 1313-1323.
15. Demets G.J-F., Triboni E.R., Alvarez E.B., Arantes G.M., Berci Fo., P. et Politi M.J. “Solvent Effects on the Photophysical
Properties of 4-Methoxy-N-methyl-1,8-Naphthalimide.” Spectrochim. Acta A 63 (2006) 220-226.
14. Bagatin I.A., Cruz A.T., Toma H.E., Politi M.J. et Demets G.J.-F “Synthesis of a Naphthalimide Functionalized Calix[4]arene;
A Host Type Fluorophore for Inclusion Compounds in Organic Medium” J. Incl. Phenom. Macroc. Chem. 52 (2005) 189–193.
13. Demets G.J. F., et Toma H.E., "Strong electric fields promote an oriented intercalative polymerization of pyrrole inside
the lamellar matrices of vanadium pentoxide.” Electrochem. Commun. 5 (2003) 74-77.
12. Anaissi F.J.,Demets G.J.-F.,Timm R.A. et Toma H.E.,"Hybridpolyaniline/bentonite/vanadium(V oxide nanocomposites.";
Mater. Sci. Eng., A. 347 (2003) 374-381.
11. Da Rocha J. R. C., Demets G. J.-F., Bertotti M., Araki K. et Toma H. E., "Charge transfer at electrostatically assembled
tetraruthenated porphyrin modified electrodes.”; J. Electroanal. Chem. 526 (2002) 69-76.
10. Demets G.J.-F., Anaissi F.J., Fontes M.B.A. et Toma H.E., "Preparation and properties of Polypyrrole/Bentonite/Vanadium(V) oxide
ternary nanocomposites."; Mater. Res. Bull. 37 (2002) 683-695.
9. Brochsztain S., Rodrigues M.A., Demets G.J.-F., et Politi M.J., "Stabilization of naphthalene 1,4:5,8-dicarboximide radicals in
zirconium phosphonate materials and thin films."; J. Mater. Chem. 12 (2002) 1250-1255.
8. Anaissi F. J., Demets G. J.-F., Alvarez E.B. , Politi M. J. et Toma H. E. , "Long term aging of V2O5.nH2O xerogel precursor solutions: structural and electrochemical implications."; Electrochim. Acta 47 (2001) 441-450.
7. Demets G. J.-F. , Toma H. E. , de Castro M. C.R. et Donnici C. L. , "Synthesis and in situ spectroscopic characterization of
electropolymerized films of 4,4’- bis[thio(mercaptomethyl)]-2,2’-bipyridine.”; J. Chem. Res. (S) (2001) 110- 112.
6. Anaissi F.J., Demets G.J.-F., Dovidauskas S., Vieira A.C. et Toma H.E., "Characterization and properties of mixed bentonite-Vanadium(V)
oxide xerogels” Mater. Res. Bull., 36-2 (2001) 289-306.
5. Demets G.J.-F., Anaissi F.J. et Toma H.E., "Electrochemical properties of assembled poly(pyrrole)/V2O5 xerogel films"; Electrochim. Acta, 46 (2000) 547-554.
4. Toyama M.M., Demets G.J.-F., Araki K., et Toma H.E., "Highly conductive electrostatically assembled porphyrazine films",
Electrochem. Commun. 2:11 (2000) 749-753.
3. Toma H.E., Serrasquiero R.M., Rocha R.C., Demets G.J.-F., Winnischofer H., Araki K., Ribeiro P.E.A et Donnici C.L.,
"Photophysical and photoelectrochemical properties of the bis(2,2 ’-bipyridine)(4,4 ’-dimethylthio-2,2 ’-bipyridine)ruthenium(II) complex",
J. Photochem. Photobiol. A 135: (2-3) (2000) 185-191.
2. Anaissi F. J., Demets G. J.-F. et Toma H. E., "Electrochemical conditioning of vanadium(V) pentoxide xerogel films",
Electrochem. Commun. 1: 8 (1999) k332-335.
1. Anaissi F. J., Demets G. J.-F. et Toma H. E., "Modified Electrodes Based on Mixed Bentonite Vanadium(V) Oxide Xerogel",
J. Electroanal. Chem., 464 (1999) 48-53.
Patent Applications
4. Triboni,E.R.;Weber,G.;Demets,G.J.F.;Politi,M.J.;De Moraes,T.B.F.; Manesco, A. L. R. "Polisilsesquioxano géis baseados em diimidas aromáticas: óptica e eletrônica", 2018 em trâmite pré-depósito na USPIN CC-PI-2018-0021 [em trâmite]
3. Lima, S. M. ; Demets, G. J.F. . PEDIDO: MEMBRANA SEMIPERMEÁVEL E SEU PROCESSO DE PRODUÇÃO. 2013, Brasil.Patente: Privilégio de Inovação. Número do registro: BR102013013197, data de depósito: 28/05/2013, título: "PEDIDO: MEMBRANA SEMIPERMEÁVEL E SEU PROCESSO DE PRODUÇÃO" , Instituição de registro:INPI - Instituto Nacional da Propriedade Industrial.
2. Demets, G. J.F. ; Silva, F. C. S. E. ; Lima, S. M. . Pedido prioritário: Esponja de matriz sólida e cucurbitu[n]urilas ou hemi-cucurbit[n]urila, processo de fabricação de esponja de matriz sólida e cucurbit[n]urila ou hemi-cucurbit[n]urila e uso de esponja de matriz sólida e cucurbit[n]urila ou hemi-cucurbit[n]urila. 2014, Brasil.Patente: Privilégio de Inovação. Número do registro: BR1020140036210, data de depósito: 17/02/2014, título: "Pedido prioritário: Esponja de matriz sólida e cucurbitu[n]urilas ou hemi-cucurbit[n]urila, processo de fabricação de esponja de matriz sólida e cucurbit[n]urila ou hemi-cucurbit[n]urila e uso de esponja de matriz sólida e cucurbit[n]urila ou hemi-cucurbit[n]urila" , Instituição de registro:INPI - Instituto Nacional da Propriedade Industrial. 1. Demets, G. J. F. ; Teodosio, T. M. B. ; Correia, H. D. ; Cavallini, T. S. . MATERIAIS SEMI-PERMEÁVEIS PARA NANOFILTRAÇÃO E USO DOS MESMOS. 2010, Brasil. Patente: Privilégio de Inovação. Número do registro: PI1002556, data de depósito: 13/07/2010, título: "MATERIAIS SEMI-PERMEÁVEIS PARA NANOFILTRAÇÃO E USO DOS MESMOS" , Instituição de registro: INPI - Instituto Nacional da Propriedade Industrial. Instituição(ões) financiadora(s): CNPq.
Tutorial Videos
Solvatocromismo solvatochromism
Comunicação científica
Divulgação/Palestras/Seminários
People
Principal investigator
Grégoire Jean-François Demets
https://orcid.org/0000-0001-7152-1266
Education and experience
- 1996- BS in Chemistry, University of São Paulo
- 2001- PhD., University of São Paulo
- 2014- Free-docency
h-Index=18, 744 citations (Jul 2022)
Honors and Awards
1996 Best poster, Anual meeting of the Brazilian Chemical Society
2008 Honored Professor, II class of licentiates in Chemistry
2008 Honorable Mention – Innovation Olympiads, University of São Paulo
2010 Honored Professor, IV class of licentiates in Chemistry
2010 Patron of the IV class of licentiates in Chemistry
2011 Patron of the V class of licentiates in Chemistry
2014 Motion of Congratulations – Chamber of Councilors, Ribeirão Preto.
Editorial Board
Orbital-the Electronic Journal of Chemistry link here
Referee for: Química Nova, Materials Research Bulletin, Synthetic Metals, Journal of Photochemistry and Photobiology. A, Chemistry, Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy,Journal of the Brazilian Chemical Society, CLEAN-Soil Air Water, Journal of Inclusion Phenomena and Macrocyclic Chemistry, Journal of Solid State Electrochemistry, Journal of Non-Crystalline Solids, Inorganic Chemistry, Crystal Growth & Design, Orbital-the Electronic Journal of Chemistry, Applied Catalysis. A-General, Sensor Letters, Supramolecular Chemistry, ACS Applied Materials & Interfaces, Journal of Coordination Chemistry, Desalination and Water Treatment
Teaches Inorganic Chemistry, Mineralogy, Polymer Chemistry and Scientific Communication.
Post-doc Fellow
Full C.V. here
Graduate Students
Full C.V. here
Undergraduate Students
Alumni
- Tiago Mateus Bezerra Teodósio, M.Sc. 2009 (Teacher)
- Érick Matheus Smaniotto dos Santos, M.Sc. 2011 (MD)
- Luis Fernando Stucchi da Silva, Ph.D. 2011 (Teacher. Colégio Marista)
- Silvânia Marilene de Lima, M. Sc., Ph. D. 2013 (INPI, Rio de Janeiro)
- Evandro Castaldelli, M.Sc.; Ph.D. 2016 (Un. Notingham, UK)
- Ulisses Fiorin Angelo, Ph.D. 2017 (Teacher. Waldorf, SEB)
- Thiago de Souza Cavallini Ph. D. 2017 (DQ-FFCLRP-USP)
- Henrique Dias Correia, Ph. D. 2017 (Teacher – ETEC – Serrana)
- Francisco de Araújo Silva, Ph. D. 2018 (Lecturer – IFSP-Sertãozinho)
- João Manoel Rocha Gonçalves, M. Sc. 2020 (IQSC-PhD; Full C.V. here)
- Renato Salviato Cicolani, Ph. D. 2020 (Teacher; Full C.V. here)
Undergraduate, Scientific initiation
- Giuliano Simoncelli Júnior
- Hélio Sbroion Rocha
- Rodrigo Francelin
- Beatriz Vivian Skalee Schneider
- Greice de Souza Vertuan
- Lucas Victorasso Jardim
- Diego Baptista
- Felipe Sousa e Silva
- Raphael Fernando Moral
- Ayla Galaço
- Victor Chadud Costacurta
- Israel Augusto da Costa e Silva
- Camila Parizzi
- Letícia Testa
- Douglas Mateus
- Guilherme Bueno Bresciani
- Filipe Canto Oliveira
- Erik Eduardo Pereira de Oliveira
- Júlio Cesar Costa de Carvalho; Full C.V. here
- Murilo Mercham Bertolucci ; Full C.V. here
- Vitória Maximino Silva; Full C.V. here
- Isabella dos Santos Abrahao; Full C.V. here
- Daniel Luis dos Santos
- Samuel Henrique de Lima
- Luiz Henrique Badan de Oliveira