Optically stimulated luminescence of Durolon polycarbonate

A.O. Silva, R. Kunzel, E.M. Yoshimura, K.C.C. Pires, N.M. Trindade.

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Highlights

  • Optically Stimulated Luminescence (OSL) of bisphenol-A polycarbonate (Durolon) was investigated;
  • Durolon presented a fast exponential decay curve, linear dose-response and a repeatable signal;
  • It was possible to describe the OSL curves with 2 components with the parameters well-established;
  • Durolon showed prominent results to act as an ionizing radiation detector.

Abstract

This paper reports for the first time the study of optically stimulated luminescence (OSL) of amorphous Brazilian bisphenol-A polycarbonate (Durolon) exposed to beta radiation. The OSL was studied from two perspectives: characterizing the luminescent signal as a function of radiation dose and examining repeatability. Computational analyses are applied to OSL curves via the deconvolution method. Fluorescence measurements employing the emission – excitation matrix (EEM) technique and optical absorption (OA) are incorporated to characterize the polymer defects and color centers. OSL measurements were carried out in a commercial reader Risø (model DA-20) coupled with a90Sr/90Y beta source. The sample was illuminated using 470 nm blue LEDs. The OSL response exhibited an exponential decay signal after 1 Gy, with linear dose-response and consistent repeatability. The continuous-wave-OSL curve was well adjusted with two distinct components. As result, Durolon promising potential as a luminescent dosimeter, supported by its desirable OSL signal characteristics.

Keywords

Durolon; OSL; Ionizing radiation; Dosimetry.

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